报告题目:Novel Clusteroluminescence Emergent from Clusterization of Non-emissive (Macro)molecules
主讲人:唐本忠 院士
时间:10月13日(周日) 16:30--17:30
地点:东校区会议中心二层报告厅
Luminescence, as a natural gift, plays an essential role in our colorful world. So far, it is believed that the development of highly efficient fluorophores relies on covalently electronic conjugation. The traditional photophysical mechanism based on through-bond conjugation seems to be perfect in explaining the luminescence of most conjugated molecules. However, some inexpensive commodity materials without any aromatic structures, such as peptides, polysaccharides, and some artificial polymers, can emit visible and bright emission. Although this phenomenon has been observed for a long time, it has not attracted much attention as the underlying mechanisms were still unclear, and these materials were hard to utilize as luminescent materials due to their low efficiency. Recent works illustrate that the single-dispersed solutions of these (macro)molecules do not emit light under UV excitation, but their aggregates can emit bright visible light. This kind of unconventional emission is named “clusteroluminescence (CL)” and the luminogens with CL characteristics are termed “clusteroluminogens (CLgens)”. Further experiments and theoretical calculations suggest that the through-space electronic interactions between the lone pairs of heteroatoms would form rigid cluster structures in the aggregate state, which ultimately emit light as achromophore. Several approaches have been developed to manipulate the performance of CLgens with controllable CL. In terms of application, CLgens always show excellent biocompatibility, which may find applications as bioimaging or tracking probes. Meanwhile, as the inter- or intra-molecular distance is sensitive to mechanical force, smart mechanically responsive materials can be developed.
主讲人简介
唐本忠,男,教授,1957年2月生。1982年获华南理工大学学士学位,1985年、1988年先后获日本京都大学硕士、博士学位。曾在多伦多大学从事博士后研究、日本NEOS公司中央研究所任高级研究员。1994–2021年在香港科技大学工作。2009年、2017年、2020年先后当选中国科学院院士、亚太材料科学院院士、发展中国家科学院院士。2021年加入香港中文大学(深圳)担任理工学院院长、校长学勤讲座教授。
已发表学术论文2,000多篇,总引用超204,200次,h因子为199。在学术会议上作了500多场邀请报告,拥有100多项授权专利。现任德国Wiley出版社发行的Aggregate《聚集体》杂志主编以及20多家国际科学杂志顾问、编委或客座编辑等。
主要从事高分子化学和先进功能材料研究。在聚集诱导发光(Aggregation-Induced Emission, AIE)这一化学和材料前沿领域取得了原创性成果,是AIE概念的提出者和AIE研究的引领者。
2014年至今连续当选全球材料和化学双领域“高被引科学家”。2007年获Croucher基金会高级研究员奖,2012年获美国化学会高分子材料科学与工程分会MACRO讲座奖,2014年获伊朗国家科技部颁发的Khwarizmi国际奖,2015年获广州市荣誉市民称号,2017年获国家自然科学一等奖、何梁何利基金科学与技术进步奖,2021年获Nano Today国际科学奖,2023年获生物材料全球影响力奖。